This is all about balancing the way the weight of the car moves around as different forces are applied to the tyres... in simple terms, a car has a fixed total weight and when static has a natural percentage of it's weight on each tyre (though the actual amount of weight and the way it's spread across the tyres will vary by car due to drive train layouts etc).
When a car is driven, the weight balance across the 4 tyres changes according to what forces are being applied... eg; braking causes a forward weight shift, accelerating a rearwards shift and turning a side shift, and then of course there's the added complication of multiple inputs... braking and turning or accelerating and turning.
As said, braking creates a forward weight shift which in effect, makes the rear of the car lighter and can reduce the amount of grip at the rear... in some cars this weight transfer can can be severe enough to cause the rear of the car to slide out when steering lock is applied at the same time as braking.
Using a bit of throttle whilst braking and turning helps control the forward weight shift by transfering some of the weight back on to the rear tyres (accelerating creates a rerwards shift).