I've ordered a fair bit if stuff from shopto over the last few years. This last year or so they start processing orders earlier (to get your card transcation process so they get the cash) but the item sits waiting to be shipped.
If shopto process orders today, I reckon you'll get charged and then the item will sit waiting for the dispatch step until Monday morning. Assuming your postie is OK you'll get it Tuesday which is still a day early....
Of course, I hope that I get mine from them this weekend but assuming this goes like Friday releases that is highly unlikely.
EDIT: Which reminds me TheHut and Zavvi are basically the same company. They sometimes have good prices but they're not a fast shipper in my experience. Most recently Football Manager 11 was delivered to me from The Hut on the Wednesday (or was it Tuesday - not sure now) after the Friday release day - that time I didn't get shipping notification until the Monday.
Rotor.